Name | Iron, dibromobis(tetrahydrofuran)- |
Synonyms | Iron, dibromobis(tetrahydrofuran)- dibromobis(tetrahydrofuran)iron(II) Iron(II) bromide, Bis(tetrahydrofuran) |
CAS | 70317-91-8 |
Molecular Formula | C8H16Br2FeO2 |
Molar Mass | 359.86444 |
Appearance | crystal |
Color | brown |
Sensitive | air sensitive, moisture sensitive |
Properties:
Iron dibromobis(tetrahydrofuran) is a white crystalline solid with good solubility in common organic solvents. It is stable in air but may undergo slight hydrolysis in the presence of moisture. Its chemical properties are mainly exhibited in catalyzing organic synthesis reactions.
Uses:
Iron dibromobis(tetrahydrofuran) is widely used as a catalyst in organic synthesis reactions, such as nucleophilic substitution of alkyl halides and aromaticity reactions of alkenes. It promotes the progress of reactions and improves the yield and purity of the products.
Synthesis:
The typical synthesis involves the reaction of iron hydroxide with hydrochloric acid to form iron chloride, followed by reaction with hydrobromic acid to obtain iron bromide. Finally, iron bromide is reacted with tetrahydrofuran to produce iron dibromobis(tetrahydrofuran). Safety precautions should be taken during the preparation process to avoid skin contact and inhalation.
Safety:
Iron dibromobis(tetrahydrofuran) should be handled with care to prevent skin and eye irritation. Proper protective gear, such as gloves and goggles, should be worn when handling this compound. It should be used in a well-ventilated area to avoid inhaling its volatile vapors. When storing, it should be kept in a dry, cool place away from sources of ignition and oxidizing agents.